Product ID:(ETHYLENEDINITRILO) TETRAACETIC ACID (SUPP
MSDS Date:03/05/1991
FSC:6810
NIIN:00N038446
MSDS Number: BRJQN

FISHER SCIENTIFIC

1 REAGENT LANE
FAIR LAWN, NJ 07410
US

Emergency Phone: 201-796-7100;800-424-9300(CHEMTREC)

Info Phone: 201-796-7100

Cage: 1B464

FISHER SCIENTIFIC CO. CHEMICAL MFG DIV

FAIRLAWN, NJ 07410-2802 US

Telephone: 201-796-7100

Cage: 1B464

RPTD/PRLNGD CONT W/SKIN

RTECS: 9999999ZZ

CONTACT WITH IRRITANTS MAY CAUSE CONJUNCTIVITIS.

RTECS: 9999999ZZ

NIOSH/MSHA APPRVD AIR-PURIFYING RESP W/HEPA

RTECS: 9999999ZZ

W/DUST & MIST FILTER.ANY NIOSH/MSHA APPRVD POWERED

RTECS: 9999999ZZ

TYPE 'C' SUPP-AIR RESP OPER IN PRESS-DEMAND/OTHER

RTECS: 9999999ZZ

ANY

RTECS: 9999999ZZ

IN PRESS-DEMAND/OTHER POS-PRESS MODE. ANY

RTECS: 9999999ZZ

OPER IN PRESS-DEMAND/OTHER POS-PRESS MODE IN

RTECS: 9999999ZZ

POSITIVE-PRESSURE MODE.

RTECS: 9999999ZZ

ACETIC ACID, (ETHYLENEDINITRILO) TETRA-, TETRASODIUM SALT;

CAS: 64-02-8

RTECS: AH5075000

Fraction By Weight: 100%

LIFTING UPPER & LOWER LIDS, UNTIL NO EVIDENCE OF

RTECS: 9999999ZZ

TREAT SYMP & SUPPORTIVELY. GET MED ATTN

RTECS: 9999999ZZ

NO SPECIFIC ANTIDOTE. TREAT

RTECS: 9999999ZZ

TOX MAY RSLT. EDTA & ITS SALTS MAY CHELATE

RTECS: 9999999ZZ

PRESENT IN INTESTINE, POSS CAUSING THEIR INCR ABSORP

RTECS: 9999999ZZ

LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE:INHAL: NO SPECIFIC DATA
AVAIL.INHAL OF DUSTS/MISTS OF EDTA SALTS MAY CAUSE MUC MEMB IRRIT
W/SORE THROAT & COUGHING. SKIN:CONT MAY CAUSE IRRIT W/REDNESS &
PAIN. APPLIC OF 500 MG TO RABBIT SKIN FO R 24 HRS RSLTD IN MOD
IRRIT. EYE: CONT MAY CAUSE IRRIT W/REDNESS & PAINT. MAY CAUSE
TRANSIENT CORNEAL (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:HLTH HAZ: INJ. SOLNS OF EDTA TETRASODIUM SALT
ARE SUFF ALKALINE TO BE INJURIOUS TO EYE.APPLIC OF 1900 UG TO
RABBIT EYES CAUSED IRRIT.APPLIC OF 100 MG/ TO RABBIT EYES FOR 24
HRS CAUSED MOD IRRIT. INGES T: SOLNS OF SALTS OF EDTA ARE
EXTREMELYIRRIT TO GI SYS. ALTHOUGH POORLY ABSORB,IF SUFF AMTS ARE
INGESTED, SYS (ING 5)
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.

First Aid:INHAL:REMOVE FROM EXPOS AREA TO FRESH AIR IMMED.IF BRTHG HAS
STOPPED, PERFORM ARTF RESP. KEEP PERSON WARM & AT REST. TREAT SYMP
& SUPPORTIVELY. GET MED ATTN IMMED. SKIN: REMOVE CONTAMD CLTHG &
SHOES I MMED. WASH AFFECTED AREA W/SOAP/MILD DETERGENT & LRG AMTS
OF WATER UNTIL NO EVIDENCE OF CHEM REMAINS (APPROX 15-20 MINS). GET
MED ATTN IMMED. EYE: WASH IMMED W/LRG AMTS OF WATER/NORM SALINE,
(SUPDAT)

Extinguishing Media:DRY CHEMICAL, CARBON DIOXIDE, WATER SPRAY OR FOAM.
FOR LARGER FIRES, USE WATER SPRAY, FOG OR ALCOHOL FOAM.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA AND FULL
PROTECTIVE EQUIPMENT . USE AGENTS SUITABLE FOR TYPE OF SURROUNDING
FIRE. AVOID BRTHG HAZ VAPS, KEEP UPWIND.
Unusual Fire/Explosion Hazard:UNKNOWN FIRE AND EXPLOSION HAZARD.

Spill Release Procedures:NO SPECIFIC PRECAUTIONS INDICATED.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:NONE SPECIFIED BY MANUFACTURER.
Other Precautions:NONE SPECIFIED BY MANUFACTURER.

Respiratory Protection:SPECIFIC RESP SELECTED MUST BE BASED ON CONTAM
LEVS FOUND IN WORK PLACE, MUST BE BASED ON SPECIFIC OPER, MUST NOT
EXCEED WORKING LIMITS OF RESP & MUST BE JOINTLY APPRVD BY
NIOSH/MSHA. ANY NIOSH/MSHA A PPRVD DUST AND MIST RESP. ANY (ING 9)
Ventilation:PROVIDE LOCAL EXHAUST VENTILATION. VENTILATION EQUIPMENT
MUST BE EXPLOSION PROOF.
Protective Gloves:IMPERVIOUS GLOVES .
Eye Protection:CHEMICAL WORKERS GOGGLES .
Other Protective Equipment:EMPLOYEE MUST WEAR APPROP PROT (IMPERVIOUS)
CLTHG & EQUIP TO PVNT RPTD/PRLNGD SKIN CONT W/SUBSTANCE. EMER EYE
(SUPDAT)
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
TRADE NAME/PART #: TETRASODIUM SALT, S-657. PH: 11.3-11.8 @ 1% SOLN.
MATLS TO AVOID: FIRE & EXPLO HAZ. OTHER PROT EQUIP: EYE WASH: WHERE
THERE IS ANY POSS THAT AN EMPLOYEE'S EYES MAY BE EXPOS TO SUBST
ANCE, EMPLOYER SHOULD PROVIDE AN EYE WASH FOUNTAIN W/IN IMMED WORK
AREA FOR EMER USE. FIRST AID PROC: OCCAS (ING 2)

Melt/Freeze Pt:M.P/F.P Text:>572F,>300C
pH:SUPDAT
Solubility in Water:SOLUBLE
Appearance and Odor:WHITE POWDER.

Stability Indicator/Materials to Avoid:YES
ACIDS:INCOMPAT. ALUMINUM: MAY FORM FLAMM HYDROGEN GAS. METALS: MAY FORM
FLAMM HYDROGEN GAS. OXIDIZERS (STRONG): (SUPDAT)
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:THERMAL DECOMPOSITION PRODUCTS MAY
INCLUDE TOXIC AND HAZARDOUS OXIDES OF CARBON, NITROGEN, AND SODIUM.

Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH FEDERAL, STATE AND
LOCAL REGULATIONS .

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.